N-(4-Chlorophenyl)benzamide
نویسندگان
چکیده
The structure of the title compound, C(13)H(10)ClNO, resembles those of N-phen-ylbenzamide, N-(2-chloro-phenyl)-benzamide and other benzanilides, with similar bond parameters. The amide group -NHCO- makes a dihedral angle of 29.95 (9)° with the benzoyl ring, while the benzoyl and aniline rings form a dihedral angle of 60.76 (3)°. The structure shows both intra- and inter-molecular hydrogen bonding. The mol-ecules are linked by N-H⋯O hydrogen bonds into chains running along the [100] direction.
منابع مشابه
2-(2-Chlorophenyl)-2,3-dihydroquinazolin-4(1H)-one
The title compound, C(14)H(11)ClN(2)O, was synthesized by the reaction of 2-chloro-benzaldehyde and 2-amino-benzamide in an ionic liquid. The pyrimidine ring adopts a skew-boat conformation and the two benzene rings make a dihedral angle of 87.1 (1)°. In the crystal, N-H⋯O and C-H⋯N hydrogen bonding links the mol-ecules along b.
متن کاملN-(4-Chlorophenyl)-2-methylbenzamide
In the structure of the title compound, C(14)H(12)ClNO, the N-H and C=O bonds are trans to each other. Furthermore, the C=O bond is syn to the ortho-methyl group in the benzoyl ring, similar to what is observed in 2-methyl-N-(4-methyl-phen-yl)benzamide and 2-methyl-N-phenyl-benzamide. The amide linkage (-NHCO-) makes dihedral angles of 36.9 (7) and 46.4 (5)° with the aniline and benzoyl rings, ...
متن کامل2,6-Dichloro-N-(4-chlorophenyl)benzamide
In the title compound, C(13)H(8)Cl(3)NO, the dihedral angle between the benzene rings is 63.2 (2)°. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into C(4) chains propagating in [001]. Weak aromatic π-π stacking also occurs [centroid-centroid separations = 3.759 (3) and 3.776 (3) Å].
متن کامل3,3′-{[(Biphenyl-2,2′-diyl)bis(methylene)]bis(oxy)}bis[N-(4-chlorophenyl)benzamide]
In the title compound, C40H30Cl2N2O4, the two benzene rings of the biphenyl unit are twisted with respect to each other, making a dihedral angle of 73.07 (4)°. The benzene rings of the benzamide groups form dihedral angles of 77.09 (5) and 55.48 (6)° with the central biphenyl moiety. In the crystal, mol-ecules are linked through N-H⋯O hydrogen bonds to form a fused R 2 (2)(38) ring motif which ...
متن کاملN-(3-Chlorophenyl)benzamide
The conformation of the N-H bond in the structure of the title compound (N3CPBA), C(13)H(10)ClNO, is anti to the meta chloro substituent in the aniline benzene ring, similar to that observed with respect to the ortho chloro substituent in N-(2-chloro-phen-yl)benzamide (N2CPBA) and meta chloro substituent in N-(3,4-dichloro-phen-yl)benzamide (N34DCPBA), but in contrast to the syn conformation ob...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008